Dataset : Crystal structure of tricarbon­yl([mu]-di­phenyl­phosphido-[kappa]2P:P)(methyl­diphenyl­silyl-[kappa]Si)bis(tri­phenyl­phosphane-[kappa]P)iron(II)platinum(0)(Fe-Pt)

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Isabelle Jourdain, Michael Knorr, Marek M. Kubicki, Ahmed Said Mohamed, Yoann Rousselin (2015): Crystal structure of tricarbon­yl([mu]-di­phenyl­phosphido-[kappa]2P:P)(methyl­diphenyl­silyl-[kappa]Si)bis(tri­phenyl­phosphane-[kappa]P)iron(II)platinum(0)(Fe-Pt). IUCr. doi:10.1107/S2056989015001565

General metadata

Identifier :local : FR-18008901306731-2016-07-19-02 external : doi:10.1107/S2056989015001565
Description :
The title compound, [FePt(C12H10P)(C13H13Si)(C18H15P)2(CO)3]·0.5CH2Cl2, represents an example of a phosphido-bridged heterobimetallic silyl complex; these are inter­esting precursors for the coordination and activation of small unsaturated organic mol­ecules. The [mu]2-PPh2 ligand spans the iron and platinum atoms, which are connected via a metal-metal bond of 2.7738 (4) Å. In contrast to most other complexes of the [(OC)3Fe(SiR3)([mu]-PR2)PtL2] family, where the iron-bound SiR3 group is trans-arranged with respect to the [mu]2-PPh2 ligand, the SiPh2Me ligand is roughly collinear with the Fe-Pt vector [Si-Fe-Pt = 169.07 (3)°].
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Keywords :

Dates :
Data acquisition : 2014
Metadata record :
Creation : 19 Jul 2016
Update : 23 Aug 2016
Issue : 1 Feb 2015

Language : English (eng)
Audience : University : master, Research

Administrative metadata

CreatorsAffiliation
Isabelle JourdainUTINAM
Michael KnorrUTINAM
Marek M. KubickiICMUB
Ahmed Said MohamedUTINAM
Yoann RousselinICMUB
Publisher : International Union of Crystallography
Science contact : Michael Knorr website e-mail
Access : available

Technical metadata

Formats : chemical/x-cif
Data acquisition methods :
Datatype : Dataset

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