Dataset : Reactivity of CuI and CuBr toward Dialkyl Sulfides RSR: From Discrete Molecular Cu4I4S4 and Cu8I8S6 Clusters to Luminescent Copper(I) Coordination Polymers

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Quotation

Antoine Bonnot, Pierre D. Harvey, Abderrahim Khatyr, Michael Knorr, Marek M. Kubicki, Antony Lapprand, Yoann Rousselin, Carsten Strohmann (2015): Reactivity of CuI and CuBr toward Dialkyl Sulfides RSR: From Discrete Molecular Cu4I4S4 and Cu8I8S6 Clusters to Luminescent Copper(I) Coordination Polymers. ACS. FR-18008901306731-2016-07-20

General metadata

Identifier :local : FR-18008901306731-2016-07-20
Description :
The CuX salts (X = I, Br) react with SR2 to form molecular clusters of the types [(R2S)4(Cu4I4)] and [(R2S)6(Cu8I8)] or to give 1D polymers and 2D metal−organic frameworks. The cluster nuclearity and connectivity as well as the dimensionality of these compounds depend on the steric demand of SR2, the solvent polarity, and the nature of the halide. These materials have been characterized by X-ray and thermogravimetric analysis and steady-state and time-resolved absorption and emission spectroscopy at 298 and 77 K.
Disciplines :
Keywords :

Dates :
Data acquisition : from 2010 to 2014
Metadata record :
Creation : 20 Jul 2016
Update : 23 Aug 2016
Issue : 6 Apr 2015

Language : English (eng)
Audience : University : master, Research

Administrative metadata

CreatorsAffiliation
Antoine BonnotUniversité de Sherbrooke
Pierre D. HarveyUniversité de Sherbrooke
Abderrahim KhatyrUTINAM
Michael KnorrUTINAM
Marek M. KubickiICMUB
Antony LapprandUTINAM
Yoann RousselinICMUB
Carsten StrohmannTU Dortmund
Publisher : American Chemical Society
Science contact : Michael Knorr website e-mail
Access : available

Technical metadata

Formats : application/pdf, chemical/x-cif
Data acquisition methods :
Datatype : Dataset

Publications

  • Reactivity of CuI and CuBr toward Dialkyl Sulfides RSR: From Discrete Molecular Cu4I4S4 and Cu8I8S6 Clusters to Luminescent Copper(I) Coordination Polymers (doi:10.1021/acs.inorgchem.5b00327)
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