Dataset : Crystal structure of di-[mu]-iodido-bis­[(dimethyl sulfoxide-[kappa]O)(tri­phenyl­phosphane-[kappa]P)copper(I)]

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Rodolphe Kinghat ; Michael Knorr ; Marek M. Kubicki ; Yoann Rousselin (2014): Crystal structure of di-[mu]-iodido-bis­[(dimethyl sulfoxide-[kappa]O)(tri­phenyl­phosphane-[kappa]P)copper(I)]. International Union of Crystallography. doi:10.25666/DATAOSU-2016-07-19-03

General metadata

Identifiers : local : FR-18008901306731-2016-07-19-03 external : doi:10.25666/DATAOSU-2016-07-19-03, ccdc:1034622, doi:10.1107/S1600536814025203
Description :
The centrosymmetric dinuclear title compound, [Cu2I2(C2H6OS)2(C18H15P)2], represents the first example of a CuI complex ligated by an O-bound dimethyl sulfoxide ligand. In the crystal, the two tetrahedrally coordinated CuI atoms are bridged by two [mu]2-iodido ligands in an almost symmetrical rhomboid geometry. The loose Cu...Cu contact of 2.9874 (8) Å is longer than the sum of the van der Waals radii of two Cu atoms (2.8 Å), excluding a significant cupriophilic inter­action in the actual dimer. C-H...O and C-H...I hydrogen bonding interactions as well as C-H...[pi](aryl) interactions stabilize the three-dimensional supramolecular network.
Disciplines :
Keywords :

Dates :
Data acquisition : 2010
Data provision : 1 Dec 2014
Metadata record :
Creation : 19 Jul 2016
Update : 24 Sep 2021

Language : English (eng)
Audience : University: master, Research

Administrative metadata

Data creatorsAffiliation
Rodolphe KinghatUTINAM (FRA)
Michael KnorrUTINAM (FRA)
Marek M. KubickiICMUB (FRA)
Yoann RousselinICMUB (FRA)
Publisher : International Union of Crystallography
Science contact : Michael Knorr website e-mail
Access : available

Technical metadata

Formats : chemical/x-cif
Data acquisition methods :
Datatype : Dataset


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