Dataset : Crystal structure of di-[mu]-iodido-bis­[bis(aceto­nitrile-[kappa]N)copper(I)]

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Eva Rebecca Barth ; Christopher Golz ; Michael Knorr ; Carsten Strohmann (2015): Crystal structure of di-[mu]-iodido-bis­[bis(aceto­nitrile-[kappa]N)copper(I)]. International Union of Crystallography. doi:10.25666/DATAOSU-2016-07-19

General metadata

Identifiers : local : FR-18008901306731-2016-07-19 external : doi:10.25666/DATAOSU-2016-07-19, ccdc:1427944, doi:10.1107/S2056989015018149
Description :
The title compound, [Cu2I2(CH3CN)4], exhibits a centrosymmetric Cu2I2 core [Cu...Cu distance = 2.7482 (11) Å], the CuI atoms of which are further coordinated by four mol­ecules of aceto­nitrile. The CuI atom has an overall distorted tetra­hedral coordination environment evidenced by L-Cu-L angles (L = N or I) ranging from 100.47 (10) to 117.06 (2)°. The coordination geometries of the aceto­nitrile ligands deviate slightly from linearity as shown by Cu-N-C angles of 167.0 (2) and 172.7 (2)°. In the crystal, there are no significant hydrogen-bonding inter­actions present, so the crystal packing seems to be formed predominantly by van der Waals forces.
Disciplines :
Keywords :

Dates :
Data acquisition : 2013
Data provision : 1 Nov 2015
Metadata record :
Creation : 19 Jul 2016
Update : 24 Sep 2021

Language : English (eng)
Audience : University: master, Research

Administrative metadata

Data creatorsAffiliation
Eva Rebecca BarthTU Dortmund (DEU)
Christopher GolzTU Dortmund (DEU)
Michael KnorrUTINAM (FRA)
Carsten StrohmannTU Dortmund (DEU)
Publisher : International Union of Crystallography
Science contact : Michael Knorr website e-mail
Access : available

Technical metadata

Formats : chemical/x-cif
Data acquisition methods :
Datatype : Dataset


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