Dataset : Two-dimensional polymeric [Hg4([mu]2-I)6I2([mu]2-C4S6)]n

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Quotation

Victoria Colquhoun, Fabrice Guyon, Aurélien Hameau, Michael Knorr, Carsten Strohmann (2011): Two-dimensional polymeric [Hg4([mu]2-I)6I2([mu]2-C4S6)]n. IUCr. doi:10.1107/S1600536811006556

General metadata

Identifier :local : FR-18008901306731-2016-07-22-02 external : doi:10.1107/S1600536811006556
Description :
The title compound, poly[([mu]2-2H,5H-1,3-dithiolo[4,5-d][1,3]di­thiole-2,5-dithione)hexa-[mu]2-iodido-diiodidotetra­mercury(II)], [Hg4I8(C4S6)]n, represents the first example of a coordination polymer assembled by the [alpha],[alpha]-C4S6 dithione ligand. The HgII ions are four-coordinated in a distorted tetra­hedral geometry, the coordination demand being satisfied either by four bridging iodide ligands or by three iodide ligands (one terminal and two bridging) and a thio­carbonyl S atom. Due to the bridging nature of the dithione ligand, the coordination polymer has a two-dimensional structure, built up of undulated layers parallel to (001). There is an inversion center at the mid-point of the central C=C double bond.
Disciplines :
chemistry, inorganic & nuclear (chemistry), crystallography (chemistry), polymer science (chemistry)
Keywords :

Dates :
Data acquisition : from 2008 to 2009
Metadata record :
Creation : 22 Jul 2016
Issue : 1 Mar 2011

Language : English (eng)
Audience : University : master, Research

Administrative metadata

Data creatorsAffiliation
Victoria ColquhounTU Dortmund
Fabrice GuyonUTINAM
Aurélien HameauUTINAM
Michael KnorrUTINAM
Carsten StrohmannTU Dortmund
Publisher : International Union of Crystallography
Science contact : Michael Knorr website e-mail
Access : available

Technical metadata

Formats : chemical/x-cif
Data acquisition methods :
Datatype : Dataset

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