Dataset : [μ-Bis(diphenylphosphanyl)methane]-tricarbonyl(μ-p-toluenesulfonylmethylisocyanato)(triphenylphosphane)iron-platinum(Fe-Pt)

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Isabelle Jourdain ; Michael Knorr ; Stephan Koller ; Carsten Strohmann (2012): [μ-Bis(diphenylphosphanyl)methane]-tricarbonyl(μ-p-toluenesulfonylmethylisocyanato)(triphenylphosphane)iron-platinum(Fe-Pt) . International Union of Crystallography. doi:10.25666/DATAOSU-2016-07-22

General metadata

Identifier : local : FR-18008901306731-2016-07-22 external : doi:10.25666/DATAOSU-2016-07-22, doi:10.1107/S1600536812004023
Description :
The title compound, [FePt(C9H9NO2S)(C18H15P)(C25H22P2)(CO)3], represents a rare example of an isonitrile-bridged heterobimetallic complex (here Pt and Fe) and is an inter­esting precursor for the preparation of heterodinuclear [mu]-amino­carbyne complexes, since the basic imine-type N atom of the [mu]2-C=N-R ligand readily undergoes addition with various electrophiles to afford iminium-like salts. In the crystal, the almost symmetrically bridging [mu]2-C=N-R ligand (neglecting the different atomic radii of Fe and Pt) is strongly bent towards the Fe(CO)3 fragment, with a C=N-R angle of only 121.1 (4)°.
Disciplines :
Keywords :

Dates :
Data acquisition : from 2011 to 2012
Data provision : 1 Mar 2012
Metadata record :
Creation : 22 Jul 2016

Language : English (eng)
Audience : University: master, Research

Administrative metadata

Data creatorsAffiliation
Isabelle JourdainUTINAM (FRA)
Michael KnorrUTINAM (FRA)
Stephan KollerTU Dortmund (DEU)
Carsten StrohmannTU Dortmund (DEU)
Publisher : International Union of Crystallography
Science contact : Michael Knorr website e-mail
Access : available

Technical metadata

Formats : chemical/x-cif
Data acquisition methods :
Datatype : Dataset


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