Reactivity of CuI and CuBr toward Dialkyl Sulfides RSR: From Discrete Molecular Cu4I4S4 and Cu8I8S6 Clusters to Luminescent Copper(I) Coordination Polymers
Collected date : from 2010 to 2014
The CuX salts (X = I, Br) react with SR2 to form molecular clusters of the types [(R2S)4(Cu4I4)] and [(R2S)6(Cu8I8)] or to give 1D polymers and 2D metal−organic frameworks. The cluster nuclearity and connectivity as well as the dimensionality of these compounds depend on the steric demand of SR2, ...
Access
Discipline
- Chemistry, analytical
- Remote sensing
- Ornithology
- Materials science, characterization & testing
- Geochemistry & geophysics
- Physiology
- Medieval & renaissance studies
- Crystallography
- Chemistry, organic
- Chemistry, physical
- Materials science, multidisciplinary
- Chemistry, inorganic & nuclear
- Polymer science