Glaciological data Austre Lovén Svalbard
These data are measured in High Arctic over an observatory basin, located at 79°N on the W coast of Svalbard. Austre Lovén is a small 4.5 km² polythermal glacier in constant decline since the end of the LIA. The surrounding catchment is no more than 10 km² and exhibits a significant periglacial area ...
Pollen analysis - La Cluse-et-Mijoux (F-25), La Cluse
Pollen tests in a white clay fill on the right bank of the Doubs. Two samples: 40 and 75 cm deep.
Pollen analysis - Vatteville-la-Rue (F-76), Mare de la Pelouse, Forêt de Brotonne
Eight pollen tests carried out on a borehole about one metre deep from a peat bog in the Brotonne forest. Samples very rich in pollen and spores. Last two millennia (Middle Ages?).
New spiropyrrolothiazole derivatives bearing an oxazolone moiety as potential antidiabetic agent: Design, synthesis, crystal structure, Hirshfeld surface analysis, ADME and molecular docking studies
In a sustained search for novel and effective antihyperglycemics, a new series of fifteen isomeric oxazolone-fused dispiropyrrolothiazoles resulting from one-pot three component reaction between L-4-thiazolidine carboxylic acid, arylidene-oxazolones and isatin (or acenaphthenequinone) has been ...
Antimicrobial Activity and DFT Studies of a Novel Set of Spiropyrrolidines Tethered with Thiochroman-4-one/Chroman-4-one Scaffolds
A novel series of 14 spiropyrrolidines bearing thiochroman-4-one/chroman-4-one, and oxindole/acenaphthylene-1,2-dione moieties were synthesized and characterized by spectroscopic techniques, as well as by three X-ray diffraction studies, corroborating the stereochemistry. Quantum chemical ...
Synthesis, antidiabetic activity and molecular docking study of rhodanine-substitued spirooxindole pyrrolidine derivatives as novel α-amylase inhibitors
In a sustained search for novel α-amylase inhibitors for the treatment of type 2 diabetes mellitus (T2DM), we report herein the synthesis of a series of nineteen novel rhodanine-fused spiro[pyrrolidine-2,3′-oxindoles]. They were obtained by one-pot three component [3 + 2] cycloaddition of stabilized ...
Pollen analysis - Vaux-lès-Saint-Claude (F-39), Eau Morte
Pollen tests in the filling of a circular depression (ice rest, pockmark?) in the heart of a meander of the Bienne. Two samples: 162 and 200 cm deep.
Diversity-oriented Synthesis of Spiropyrrolo[1, 2-a]isoquinoline Derivatives via Diastereoselective and Regiodivergent Three-component 1,3-Dipolar Cycloaddition Reactions: In vitro and in vivo Evaluation of the Antidiabetic Activity of Rhodanine Analogues
An efficient diastereoselective route is developed to get access to novel spiropyrrolo[1,2-a]isoquinoline-oxindole skeletons by a one-potthree-component [3 + 2] cycloaddition reaction of (Z)-5-arylidene-1,3-thiazolidine-2,4-diones, isatin derivatives, and 1,2,3,4-tetrahydroisoquinoline (THIQ). ...
Control of Structures and Emission Properties of (CuI)n 2-Methyldithiane Coordination Polymers
A structurally unique and strongly luminescent nonporous 3D coordination polymer (CP) [Cu8I8(methyldithiane)4]n, CP3, has been prepared in a quasi-anticipated manner from 2-methyl-1,3-dithiane, L1, and CuI. This CP incorporates an unprecedented Cu8I8 cluster built upon two side-fused open cubanes. ...
A Fused Poly(truncated rhombic dodecahedron)-Containing 3D Coordination Polymer: A Multifunctional Material with Exceptional Properties
The design of new and inexpensive metal-containing functional materials is of great interest. Herein is reported a unique thermochromic near-IR emitting coordination polymer, 3D-[Cu8I8(L1)2]n, CP2, which is formed when ArS(CH2)4SAr (L1, Ar = 4-C6H4OMe) reacts with 2 equiv of CuI in EtCN. In MeCN, ...
Crystal structure of di-[mu]-iodido-bis[bis(acetonitrile-[kappa]N)copper(I)]
The title compound, [Cu2I2(CH3CN)4], exhibits a centrosymmetric Cu2I2 core [Cu...Cu distance = 2.7482 (11) Å], the CuI atoms of which are further coordinated by four molecules of acetonitrile. The CuI atom has an overall distorted tetrahedral coordination environment evidenced by L-Cu-L angles (L ...
Crystal structure of di-[mu]-iodido-bis[(dimethyl sulfoxide-[kappa]O)(triphenylphosphane-[kappa]P)copper(I)]
The centrosymmetric dinuclear title compound, [Cu2I2(C2H6OS)2(C18H15P)2], represents the first example of a CuI complex ligated by an O-bound dimethyl sulfoxide ligand. In the crystal, the two tetrahedrally coordinated CuI atoms are bridged by two [mu]2-iodido ligands in an almost symmetrical ...
Crystal structure of the two-dimensional coordination polymer poly[di-μ-bromido-bis(μ-tetrahydrothiophene)dicopper(I)]
The polymeric title compound, [Cu2Br2(C4H8S)2]n, CP1, represents an example of a two-dimensional coordination polymer resulting from reaction of CuBr with tetrahydrothiophene (THT) in MeCN solution. The two-dimensional layers consist of two different types of rhomboid-shaped dinuclear ...
Pollen analysis - Fontenu (F-39), îlot David-1987, FG 30, 86 S-C, 86 G23
Archaeological site. Lake dwelling. 9 palynological samples (related to M. Magny PhD thesis, 1991).
Pollen analysis - Grozon (F-39), L'étang (Marais)
Natural site: wooded swamp. 144 palynological samples with 2 radiocarbon datings. Sometimes quite poor. Further analyses were done in the village of Grozon around the salt springs by E. Gauthier (PhD, 2001).
Pollen analysis - Bonlieu (F-39), Le Lautrey (point 205)
Peat bog; 51 palynological samples. Other analyses on this site by Carole Bégeot and Pascale Ruffaldi (2006)
Pollen analysis - Montlebon (F-25), Sur la Vigne 1 (Morteau A)
Natural site: wet meadow. 99 palynological samples + 4 radiocarbon datings. Drilling of 28.10 meters length.
Pollen analysis - Montlebon (F-25), La Vigne 2
Natural site: wet meadow. 22 palynological samples. From 3,90 to 18,85 meters length: extension of Morteau Stade and Sur la Seigne transect lines.
Pollen analysis - La-Chaux-du-Dombief (F-39), Lac d'Ilay 1989
Natural site: peat bog border on the lake. 10 palynological samples.
Pollen analysis - Fontenu (F-39), Lac de Chalain, Station 3-1986 (îlot David)
Archaeological site. Lake dwelling. 5 palynological samples (related to M. Magny PhD thesis, 1991).
Pollen analysis - Le Frasnois (F-39), Lac du Petit-Maclu
Natural site: peat bog border on the lake. 31 palynological samples.
Pollen analysis - Etival (F-39), Petit lac
Natural site, peat bog border on the lake. 6 palynological samples (related to M. Magny PhD thesis, 1991).
Pollen analysis - Etival (F-39), Grand lac
Natural site, peat bog border on the lake. 16 palynological samples (related to M. Magny PhD thesis, 1991).
Pollen analysis - Lavancia-Epercy (F-39), Dortan travertine quarry
Natural site: travertine quarry ("Tuff of Dortan"). 3 palynological samples + 1 radiocarbon dating: 9100 ± 180 BP.
Pollen analysis - Montlebon (F-25), Transect S4
Natural site: wet meadow. 6 palynological samples. From 10.20 to 13.20 meters. Atypical results. Extension of Morteau Stade et Sur la Seigne transect lines.
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