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Redetermination of the crystal structure of tetrammineplatinum(II) dichloride – A microporous hydrogen-bonded 3D network exhibiting a temperature-dependent order-disorder phase transition

The title compound [Pt(NH3)4]Cl2 (1), prepared by reaction of (NH4)2[PtCl4] with an excess of NH3 in aqueous solution, was crystallized from water and its structure redetermined by single-crystal X-ray diffraction at four different temperatures in the range from 273 K down to 100 K. 1 is composed of ...

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Heterodinuclear Diphosphane-Bridged Iron–Platinum Diyne Complexes as Metalloligands for the Assembly of Polymetallic Systems (Fe, Pt, Co)

Treatment of [(OC)3Fe(μ-C=O)(µ-dppm)Pt(PPh3)] (1a) (dppm=Ph2PCH2PPh2) with 1,7-octadiyne affords the isomeric dimetallacyclopentenones [(OC)2Fe(µ-dppm)(µ-C(=O)C{(CH2)4C≡CH}=CH)Pt(PPh3)] (2a) and [(OC)2Fe(µ-dppm)(µ-C(=O)C(H)=C{(CH2)4C≡CH})Pt(PPh3)] (2a′). In a similar manner, the reaction with ...

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Wetland functionning and functional traits of Nuphar lutea

Dataset
Collected date : from Apr 2015 to Mar 2016

Eleven populations of Nuphar lutea were sampled in eleven wetlands differing in physicochemical characteristics and spread along three rivers (the Ain, the Doubs and the Loue Rivers). Fifteen traits, grouped into four sets (growth, reproduction, storage and defence), were measured during the growing ...

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Pollen analysis - Omisalj (Croatia)

Dataset
Collected date : from Jun 2018 ongoing
Labels : I-SITE BFC
Creators : Benjamin Dietre

Pollen analysis conducted in 2018 from a sediment core recovered in 2016 (OMISALJ-2016) at Omisalj, Krk Island.

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Pollen analysis - Osor (Croatia)

Dataset
Collected date : from Jun 2018 ongoing
Labels : I-SITE BFC
Creators : Benjamin Dietre

Pollen analysis conducted in 2018 from a sediment core recovered in 2016 (OSOR-2016) at Osor, Cres Island.

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Googlomics: Inferring hidden causal relations between pathway members using reduced Google matrix of directed biological networks

Signaling pathways represent parts of the global biological network which connects them into a seamless whole through complex direct and indirect (hidden) crosstalk whose structure can change during normal development or in a pathological conditions such as cancer. Advanced methods for ...

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Pollen analyses - Dizy (CH-VD), En Delèze

Dataset
Collected date : from 2015 to 2016

Pollen analyses conducted in 2015 from a sediment core recovered in 2014 (Dizy-2014) at En Delèze, Dizy.

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Pollen analyses - Les Hôpitaux-Vieux (F-25), La Beuffarde

Dataset
Collected date : from 2017 ongoing
Labels : ZAAJ
Creators : Benjamin Dietre

Pollen analyses conducted in 2017 from a sediment core recovered in 2016 (BEUF-2016) at La Beuffarde, Les Hôpitaux-Vieux.

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Pollen analyses - Alba-la-Romaine (F-07), La Grande Terre

Dataset
Collected date : from Oct 2015 ongoing
Creators : Benjamin Dietre

Pollen analyses conducted in 2015 from 23 soil samples recovered in 2015 at La Grande Terre, Alba-la-Romaine.

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Pollen analyses - L'Auberson (CH-VD), Les Araignys

Dataset
Collected date : from 2017 ongoing
Labels : ZAAJ
Creators : Benjamin Dietre

Pollen analyses conducted in 2017 from a sediment core recovered in 2015 (ARA-2015) at Les Araignys, L'Auberson.

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Pollen analyses - Labergement-Sainte-Marie (F-25), Remoray Lake

Dataset
Collected date : from 2016 ongoing
Creators : Benjamin Dietre

Pollen analyses conducted in 2017 from a sediment core recovered in 2007 (REM-07) at Remoray Lake.

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Crystal structure of di-[mu]-iodido-bis­[bis(aceto­nitrile-[kappa]N)copper(I)]

The title compound, [Cu2I2(CH3CN)4], exhibits a centrosymmetric Cu2I2 core [Cu...Cu distance = 2.7482 (11) Å], the CuI atoms of which are further coordinated by four mol­ecules of aceto­nitrile. The CuI atom has an overall distorted tetra­hedral coordination environment evidenced by L-Cu-L angles (L ...

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Crystal structure of di-[mu]-iodido-bis­[(dimethyl sulfoxide-[kappa]O)(tri­phenyl­phosphane-[kappa]P)copper(I)]

The centrosymmetric dinuclear title compound, [Cu2I2(C2H6OS)2(C18H15P)2], represents the first example of a CuI complex ligated by an O-bound dimethyl sulfoxide ligand. In the crystal, the two tetrahedrally coordinated CuI atoms are bridged by two [mu]2-iodido ligands in an almost symmetrical ...

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Crystal structure of tricarbon­yl([mu]-di­phenyl­phosphido-[kappa]2P:P)(methyl­diphenyl­silyl-[kappa]Si)bis(tri­phenyl­phosphane-[kappa]P)iron(II)platinum(0)(Fe-Pt)

The title compound, [FePt(C12H10P)(C13H13Si)(C18H15P)2(CO)3]·0.5CH2Cl2, represents an example of a phosphido-bridged heterobimetallic silyl complex; these are inter­esting precursors for the coordination and activation of small unsaturated organic mol­ecules. The [mu]2-PPh2 ligand spans the iron and ...

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Bis{(4-methylthio)phenylthio}methane as assembling ligand for the construction of Cu(I) and Hg(II) coordination polymers. Crystal structures and topological (AIM) analysis of the bonding

The novel 1D coordination polymer (CP) [{Cu(μ2-Br)2Cu}(μ-L2)2] CP2 has been obtained by reaction of the tetrakisthioether p-MeSC6H4SCH2SC6H4SMe-p (L2) with CuBr in a 1:2 metal-to ligand ratio. In contrast to the previously described CP [{Cu(μ2-Br)2Cu}(μ-L1)2] CP1 obtained by reaction of the ...

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2-(2,2-Dibromo­ethen­yl)thio­phene

The title compound, C6H4Br2S, represents a versatile building block for the preparation of [pi]-conjugated redox-active thienyl oligomers and metal-mediated cross-coupling reactions. This is due to the presence of an electrochemically active thienyl heterocycle and a reactive dibromo­vinyl ...

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Two-dimensional polymeric [Hg4([mu]2-I)6I2([mu]2-C4S6)]n

The title compound, poly[([mu]2-2H,5H-1,3-dithiolo[4,5-d][1,3]di­thiole-2,5-dithione)hexa-[mu]2-iodido-diiodidotetra­mercury(II)], [Hg4I8(C4S6)]n, represents the first example of a coordination polymer assembled by the [alpha],[alpha]-C4S6 dithione ligand. The HgII ions are four-coordinated in a ...

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[μ-Bis(diphenylphosphanyl)methane]-tricarbonyl(μ-p-toluenesulfonylmethylisocyanato)(triphenylphosphane)iron-platinum(Fe-Pt)

The title compound, [FePt(C9H9NO2S)(C18H15P)(C25H22P2)(CO)3], represents a rare example of an isonitrile-bridged heterobimetallic complex (here Pt and Fe) and is an inter­esting precursor for the preparation of heterodinuclear [mu]-amino­carbyne complexes, since the basic imine-type N atom of the ...

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