Digitized inventory of the French peatlands of 1949
Digitized data from the French peatland inventory ("Les tourbières françaises", Ministry of Industry and Trade, 1949). This national inventory was carried out in order to estimate the stock of peat in metropolitan France and to facilitate its exploitation, essentially for fuel purposes. Thus, a ...
Glaciological data Austre Lovén Svalbard
These data are measured in High Arctic over an observatory basin, located at 79°N on the W coast of Svalbard. Austre Lovén is a small 4.5 km² polythermal glacier in constant decline since the end of the LIA. The surrounding catchment is no more than 10 km² and exhibits a significant periglacial area ...
New spiropyrrolothiazole derivatives bearing an oxazolone moiety as potential antidiabetic agent: Design, synthesis, crystal structure, Hirshfeld surface analysis, ADME and molecular docking studies
In a sustained search for novel and effective antihyperglycemics, a new series of fifteen isomeric oxazolone-fused dispiropyrrolothiazoles resulting from one-pot three component reaction between L-4-thiazolidine carboxylic acid, arylidene-oxazolones and isatin (or acenaphthenequinone) has been ...
Antimicrobial Activity and DFT Studies of a Novel Set of Spiropyrrolidines Tethered with Thiochroman-4-one/Chroman-4-one Scaffolds
A novel series of 14 spiropyrrolidines bearing thiochroman-4-one/chroman-4-one, and oxindole/acenaphthylene-1,2-dione moieties were synthesized and characterized by spectroscopic techniques, as well as by three X-ray diffraction studies, corroborating the stereochemistry. Quantum chemical ...
Synthesis, antidiabetic activity and molecular docking study of rhodanine-substitued spirooxindole pyrrolidine derivatives as novel α-amylase inhibitors
In a sustained search for novel α-amylase inhibitors for the treatment of type 2 diabetes mellitus (T2DM), we report herein the synthesis of a series of nineteen novel rhodanine-fused spiro[pyrrolidine-2,3′-oxindoles]. They were obtained by one-pot three component [3 + 2] cycloaddition of stabilized ...
Pressure-Temperature quantification of continental crustal hydration - Colorado Plateau
Data acquired in collaboration with the University of Boulder in Colorado (U.S.A.) for the understanding of the Colorado Plateau elevation. These data sets include mineralogical, petrological, chemical, pressure-temperature modelisation and density evolution.
Crystal structure of di-[mu]-iodido-bis[bis(acetonitrile-[kappa]N)copper(I)]
The title compound, [Cu2I2(CH3CN)4], exhibits a centrosymmetric Cu2I2 core [Cu...Cu distance = 2.7482 (11) Å], the CuI atoms of which are further coordinated by four molecules of acetonitrile. The CuI atom has an overall distorted tetrahedral coordination environment evidenced by L-Cu-L angles (L ...
Crystal structure of di-[mu]-iodido-bis[(dimethyl sulfoxide-[kappa]O)(triphenylphosphane-[kappa]P)copper(I)]
The centrosymmetric dinuclear title compound, [Cu2I2(C2H6OS)2(C18H15P)2], represents the first example of a CuI complex ligated by an O-bound dimethyl sulfoxide ligand. In the crystal, the two tetrahedrally coordinated CuI atoms are bridged by two [mu]2-iodido ligands in an almost symmetrical ...
WRF-CORDEX simulations on the Mediterranean domain MED-44
WRF-CORDEX simulations on the Mediterranean MED-44 domain at 44 kms resolution. The version of the WRF model is 3.8.1 (Advance Research WRF dynamics (Skamarock et al 2008.)) forced by ERA-interim for the control run and CCSM4 for the scenarios. 4 sets of data are therefore available: the control run ...
WRF-CORDEX simulations on the Europe domain EUR-44
WRF-CORDEX simulations on the European EUR-44 domain at 44 kms resolution. The version of the WRF model is 3.8.1 (Advance Research WRF dynamics (Skamarock et al 2008.)) forced by ERA-interim for the control run and CCSM4 for the scenarios. 4 sets of data are therefore available: the control run over ...
Pollen analysis - Dizy (Suisse, Vaud), En Delèze
Two series of pollen analyses at En Delèze, Dizy. Natural site: peat bog. Series 1: Samples from three trenches (M20, M25 et M80) Series 2: Drilling with a mechanized Russian core (DZ6) All together, 289 samples analysed and 18 14C dates.
Redetermination of the crystal structure of tetrammineplatinum(II) dichloride – A microporous hydrogen-bonded 3D network exhibiting a temperature-dependent order-disorder phase transition
The title compound [Pt(NH3)4]Cl2 (1), prepared by reaction of (NH4)2[PtCl4] with an excess of NH3 in aqueous solution, was crystallized from water and its structure redetermined by single-crystal X-ray diffraction at four different temperatures in the range from 273 K down to 100 K. 1 is composed of ...
Heterodinuclear Diphosphane-Bridged Iron–Platinum Diyne Complexes as Metalloligands for the Assembly of Polymetallic Systems (Fe, Pt, Co)
Treatment of [(OC)3Fe(μ-C=O)(µ-dppm)Pt(PPh3)] (1a) (dppm=Ph2PCH2PPh2) with 1,7-octadiyne affords the isomeric dimetallacyclopentenones [(OC)2Fe(µ-dppm)(µ-C(=O)C{(CH2)4C≡CH}=CH)Pt(PPh3)] (2a) and [(OC)2Fe(µ-dppm)(µ-C(=O)C(H)=C{(CH2)4C≡CH})Pt(PPh3)] (2a′). In a similar manner, the reaction with ...
Pollen analysis - Omisalj (Croatia)
Pollen analysis conducted in 2018 from a sediment core recovered in 2016 (OMISALJ-2016) at Omisalj, Krk Island.
Pollen analysis - Osor (Croatia)
Pollen analysis conducted in 2018 from a sediment core recovered in 2016 (OSOR-2016) at Osor, Cres Island.
Googlomics: Inferring hidden causal relations between pathway members using reduced Google matrix of directed biological networks
Signaling pathways represent parts of the global biological network which connects them into a seamless whole through complex direct and indirect (hidden) crosstalk whose structure can change during normal development or in a pathological conditions such as cancer. Advanced methods for ...
Pollen analyses - Les Hôpitaux-Vieux (F-25), La Beuffarde
Pollen analyses conducted in 2017 from a sediment core recovered in 2016 (BEUF-2016) at La Beuffarde, Les Hôpitaux-Vieux.
Pollen analyses - Alba-la-Romaine (F-07), La Grande Terre
Pollen analyses conducted in 2015 from 23 soil samples recovered in 2015 at La Grande Terre, Alba-la-Romaine.
Pollen analyses - L'Auberson (CH-VD), Les Araignys
Pollen analyses conducted in 2017 from a sediment core recovered in 2015 (ARA-2015) at Les Araignys, L'Auberson.
Pollen analyses - Labergement-Sainte-Marie (F-25), Remoray Lake
Pollen analyses conducted in 2017 from a sediment core recovered in 2007 (REM-07) at Remoray Lake.
Monthly mean interpolated climatic fields for Kenya
Long-term mean monthly interpolated climatic data (minimum temperature, maximum temperature, precipitation amounts, parameters of Markov chains and gamma distribution for daily rainfall, solar radiation, relative humidity, wind speed) for Kenya (5.35°S to 4.32°N, 33.70°E to 41.95°E) at a resolution ...
Crystal structure of tricarbonyl([mu]-diphenylphosphido-[kappa]2P:P)(methyldiphenylsilyl-[kappa]Si)bis(triphenylphosphane-[kappa]P)iron(II)platinum(0)(Fe-Pt)
The title compound, [FePt(C12H10P)(C13H13Si)(C18H15P)2(CO)3]·0.5CH2Cl2, represents an example of a phosphido-bridged heterobimetallic silyl complex; these are interesting precursors for the coordination and activation of small unsaturated organic molecules. The [mu]2-PPh2 ligand spans the iron and ...
Bis{(4-methylthio)phenylthio}methane as assembling ligand for the construction of Cu(I) and Hg(II) coordination polymers. Crystal structures and topological (AIM) analysis of the bonding
The novel 1D coordination polymer (CP) [{Cu(μ2-Br)2Cu}(μ-L2)2] CP2 has been obtained by reaction of the tetrakisthioether p-MeSC6H4SCH2SC6H4SMe-p (L2) with CuBr in a 1:2 metal-to ligand ratio. In contrast to the previously described CP [{Cu(μ2-Br)2Cu}(μ-L1)2] CP1 obtained by reaction of the ...
2-(2,2-Dibromoethenyl)thiophene
The title compound, C6H4Br2S, represents a versatile building block for the preparation of [pi]-conjugated redox-active thienyl oligomers and metal-mediated cross-coupling reactions. This is due to the presence of an electrochemically active thienyl heterocycle and a reactive dibromovinyl ...
Two-dimensional polymeric [Hg4([mu]2-I)6I2([mu]2-C4S6)]n
The title compound, poly[([mu]2-2H,5H-1,3-dithiolo[4,5-d][1,3]dithiole-2,5-dithione)hexa-[mu]2-iodido-diiodidotetramercury(II)], [Hg4I8(C4S6)]n, represents the first example of a coordination polymer assembled by the [alpha],[alpha]-C4S6 dithione ligand. The HgII ions are four-coordinated in a ...
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