MEDUSA: Marine benthic Ecological Data from Underwater imagery Surveys of sub-Antarctic Crozet environments
Inscribed on the UNESCO World Heritage list, the sub-Antarctic Crozet archipelago is located in a region facing significant environmental changes impacting a poorly known marine biodiversity. Underwater imagery constitutes a valuable non-invasive approach for gathering ecological data and improving ...
PROTEKER: a near-shore submarine observatory in the Kerguelen Islands for the long-term monitoring of benthic habitats
PROTEKER is a pilot program that aims at establishing a baseline for assessing the impact of climate change on near-shore marine ecosystems of the Kerguelen Islands by implementing an ecological and genetic monitoring at reference sites. The high diversity of coastal marine ecosystems is usually ...
4’-(N-(2-cyanoethyl)pyrrol-2-yl)-2,2’:6’,2’’-terpyridine
Data for the synthesis and caracterization of 4’-(N-(2-cyanoethyl)pyrrol-2-yl)-2,2’:6’,2’’-terpyridine.
4′-(N-(Propargyl)pyrrol-2-yl)-2,2′:6′,2′′-terpyridine
A new terpyridine molecule, bearing a N-propargylated pyrrole, was prepared and characterized. Its synthesis was based on a Krohnke-type reaction between 2-acetylpyridine and N-propargylpyrrole-2-carboxaldehyde in a basic medium. An allene-containing terpyridine was also obtained as a by-product.
1-{4-[(Hexyloxy)methyl]pyridin-2-yl}ethanone
A new member of the 2-acetylpyridine family has been prepared and characterized by NMR and IR spectroscopies.
New spiropyrrolothiazole derivatives bearing an oxazolone moiety as potential antidiabetic agent: Design, synthesis, crystal structure, Hirshfeld surface analysis, ADME and molecular docking studies
In a sustained search for novel and effective antihyperglycemics, a new series of fifteen isomeric oxazolone-fused dispiropyrrolothiazoles resulting from one-pot three component reaction between L-4-thiazolidine carboxylic acid, arylidene-oxazolones and isatin (or acenaphthenequinone) has been ...
Antimicrobial Activity and DFT Studies of a Novel Set of Spiropyrrolidines Tethered with Thiochroman-4-one/Chroman-4-one Scaffolds
A novel series of 14 spiropyrrolidines bearing thiochroman-4-one/chroman-4-one, and oxindole/acenaphthylene-1,2-dione moieties were synthesized and characterized by spectroscopic techniques, as well as by three X-ray diffraction studies, corroborating the stereochemistry. Quantum chemical ...
Synthesis, antidiabetic activity and molecular docking study of rhodanine-substitued spirooxindole pyrrolidine derivatives as novel α-amylase inhibitors
In a sustained search for novel α-amylase inhibitors for the treatment of type 2 diabetes mellitus (T2DM), we report herein the synthesis of a series of nineteen novel rhodanine-fused spiro[pyrrolidine-2,3′-oxindoles]. They were obtained by one-pot three component [3 + 2] cycloaddition of stabilized ...
Modelling the response of Antarctic marine species to environmental changes. Methods, applications and limitations
Ecological modelling is nowadays widely used to highlight the environmental conditions that influence the species ecological niche and better understand their response to environmental changes. Methodological challenges are however present for Southern Ocean marine case studies and it is important ...
1-(4-Formyl-2,6-dimethoxyphenoxy)-4-chlorobut-2-yne
A reaction of biomass-derived aldehyde synringaldehyde and half an equivalent of 1,4-dichlorobut-2-yne was attempted in order to obtain a bis-aldehyde with an alkyne spacer. The reaction was carried out in a basic media to effect bis O-alkylation, as described in literature for the preparation of ...
4′-(5-Methylfuran-2-yl)-2,2′:6′,2″-terpyridine: A New Ligand Obtained from a Biomass-Derived Aldehyde with Potential Application in Metal-Catalyzed Reactions
The new ligand 4′-(5-methylfuran-2-yl)-2,2′:6′,2″-terpyridine (1) was prepared in one step from 2-acetylpyridine and 5-methylfurfural. The latter is an aldehyde that can be readily obtained from biomass. The new terpyridine molecule was characterized by 1H and 13C-NMR spectroscopy as well as by ...
Diversity-oriented Synthesis of Spiropyrrolo[1, 2-a]isoquinoline Derivatives via Diastereoselective and Regiodivergent Three-component 1,3-Dipolar Cycloaddition Reactions: In vitro and in vivo Evaluation of the Antidiabetic Activity of Rhodanine Analogues
An efficient diastereoselective route is developed to get access to novel spiropyrrolo[1,2-a]isoquinoline-oxindole skeletons by a one-potthree-component [3 + 2] cycloaddition reaction of (Z)-5-arylidene-1,3-thiazolidine-2,4-diones, isatin derivatives, and 1,2,3,4-tetrahydroisoquinoline (THIQ). ...
4,4″-Dichloro-4′-(2-thienyl)-2,2′:6′,2″-terpyridine
A new thiophene-substituted terpyridine derivative has been prepared and characterized. This ligand features a thiophene heterocycle (as an electrochemically polymerizable unit) as well as two chlorine atoms for further functionalization.
4′-(N-(Propan-1,2-dienyl)pyrrol-2-yl)-2,2′:6′,2″-terpyridine
A new pyrrole-substituted terpyridine derivative that possesses an allene moiety was obtained as an “unexpected” sole product during an attempt to alkylate the N-atom of pyrrole with propargyl bromide in order to obtain an alkyne-functionalized terpyridine.
4′-(5-n-Propylthiophen-2-yl)-2,2′:6′,2″-terpyridine
A new thiophene-substituted terpyridine derivative has been prepared through the reaction between 5-n-propylthiophene-2-carboxaldehyde and 2-acetylpyridine. This terpyridine derivative bears an alkyl chain linked via a thiophene heterocycle.
Pollen analysis - Le Miroir (F-71), La Tuilerie (La Peupleraie), A39-T1 and T2
Natural site over the alignment of the A39 motorway; drilling. Two series: T1 (18 poor samples) and T2 (88 palynological samples + 2 radiocarbon datings). Samples often difficult to read. Publication CRAS, 1996.
Pollen analysis - Auneau (F-28), L'Hermitage (detour road 18/116/19)
Natural site: drilling with motorised "russian" core. 120 palynological samples. + 6 radiocarbon datings. 2015 publication: only the "gallo-roman" part.
Pollen analysis - Villers-le-Lac (F-25), La Roche aux pêcheurs
Archaeological site: rock shelter. 10 palynological samples. Only one acceptable result. Archaeological excavation: Ch. Cupillard, SRA de Franche-Comté.
Pollen analysis - Fontenu (F-39), îlot David-1987, FG 30, 86 S-C, 86 G23
Archaeological site. Lake dwelling. 9 palynological samples (related to M. Magny PhD thesis, 1991).
Pollen analysis - Fontenu (F-39), Lac de Chalain, îlot David, A 33/34
Archaeological site. Lake dwelling. 11 palynological samples.
Pollen analysis - Héricourt (F-70), La Lizaine (chemin de l'usine)
Archaeological excavation of rural settlement. 7 palynological samples. Approximate geographical coordinates.
Pollen analysis - Grozon (F-39), L'étang (Marais)
Natural site: wooded swamp. 144 palynological samples with 2 radiocarbon datings. Sometimes quite poor. Further analyses were done in the village of Grozon around the salt springs by E. Gauthier (PhD, 2001).
Pollen analysis - Clairvaux-les-lacs (F-39), Station II
Archaeological site. Lake dwelling. 14 palynological samples + radiocarbon and dendrochronological datings.
Pollen analysis - Bonlieu (F-39), Le Lautrey (point 205)
Peat bog; 51 palynological samples. Other analyses on this site by Carole Bégeot and Pascale Ruffaldi (2006)
Pollen analysis - Andelot-en-Montagne (F-39), Marais (KTH)
Peat bog. 9 palynological samples. KTH testing (see : Sjörgen, P. 2007. Mires and Peat, International Mire Conservation Group and International Peat Society ; Gobet, 2014)
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