66 results

4’-(N-(2-cyanoethyl)pyrrol-2-yl)-2,2’:6’,2’’-terpyridine

Disciplines : chemistry, organic
Collected date : Jun 2022
Creators : Jérôme Husson

Data for the synthesis and caracterization of 4’-(N-(2-cyanoethyl)pyrrol-2-yl)-2,2’:6’,2’’-terpyridine.

4′-(N-(Propargyl)pyrrol-2-yl)-2,2′:6′,2′′-terpyridine

Disciplines : chemistry, organic
Collected date : from 2018 to 2019

A new terpyridine molecule, bearing a N-propargylated pyrrole, was prepared and characterized. Its synthesis was based on a Krohnke-type reaction between 2-acetylpyridine and N-propargylpyrrole-2-carboxaldehyde in a basic medium. An allene-containing terpyridine was also obtained as a by-product.

Satellite images of cloud types products in West Africa from March to August in 2017

It is products developped by Meteo France through the SAF application, showing the types of clouds in function of their elevation.

1-{4-[(Hexyloxy)methyl]pyridin-2-yl}ethanone

Disciplines : chemistry, organic
Collected date : 2016
Creators : Florian Charrier

A new member of the 2-acetylpyridine family has been prepared and characterized by NMR and IR spectroscopies.

SISMEAUCLIM

This project is based on three disciplines: seismology, hydrogeology and climatology. It aims to develop a new approach to monitor hydrogeological reservoirs, in particular karst aquifers, subject to extreme climatic events. The objective is to carry out 4D imaging during floods in a watershed ...

New spiropyrrolothiazole derivatives bearing an oxazolone moiety as potential antidiabetic agent: Design, synthesis, crystal structure, Hirshfeld surface analysis, ADME and molecular docking studies

In a sustained search for novel and effective antihyperglycemics, a new series of fifteen isomeric oxazolone-fused dispiropyrrolothiazoles resulting from one-pot three component reaction between L-4-thiazolidine carboxylic acid, arylidene-oxazolones and isatin (or acenaphthenequinone) has been ...

Antimicrobial Activity and DFT Studies of a Novel Set of Spiropyrrolidines Tethered with Thiochroman-4-one/Chroman-4-one Scaffolds

A novel series of 14 spiropyrrolidines bearing thiochroman-4-one/chroman-4-one, and oxindole/acenaphthylene-1,2-dione moieties were synthesized and characterized by spectroscopic techniques, as well as by three X-ray diffraction studies, corroborating the stereochemistry. Quantum chemical ...

Synthesis, antidiabetic activity and molecular docking study of rhodanine-substitued spirooxindole pyrrolidine derivatives as novel α-amylase inhibitors

In a sustained search for novel α-amylase inhibitors for the treatment of type 2 diabetes mellitus (T2DM), we report herein the synthesis of a series of nineteen novel rhodanine-fused spiro[pyrrolidine-2,3′-oxindoles]. They were obtained by one-pot three component [3 + 2] cycloaddition of stabilized ...

Mesures urbaines de la température dans l’agglomération du Grand Dijon (MUSTARDijon)

Collected date : from Sep 2014 ongoing

Air temperature and monitoring in the Dijon agglomeration for high-resolution monitoring of the urban heat island (50 stations, record sampling every 20 minutes, period June 2014 onwards)

Descriptors monitoring atmospheric centers of action of weather patterns around Aotearoa New Zealand

Collected date : from 2021 ongoing

Here we introduce a set of descriptors applied to weather regimes that allow for a detailed monitoring of the location and intensity of their atmospheric centers of action (e.g., troughs and ridges) and the gradients between them, when applicable. Descriptors are designed to document the effect of ...

Mobile temperature measurements of air temperature in Dijon

Air temperature and monitoring in the Dijon agglomeration by bike (one measurement every 5m) to characterize the urban heat island at very high resolution along constant transects

1-(4-Formyl-2,6-dimethoxyphenoxy)-4-chlorobut-2-yne

Disciplines : chemistry, organic
Collected date : from 2020 to 2021
Creators : Jérôme Husson

A reaction of biomass-derived aldehyde synringaldehyde and half an equivalent of 1,4-dichlorobut-2-yne was attempted in order to obtain a bis-aldehyde with an alkyne spacer. The reaction was carried out in a basic media to effect bis O-alkylation, as described in literature for the preparation of ...

4′-(5-Methylfuran-2-yl)-2,2′:6′,2″-terpyridine: A New Ligand Obtained from a Biomass-Derived Aldehyde with Potential Application in Metal-Catalyzed Reactions

Disciplines : chemistry, organic
Collected date : from 2017 to 2018

The new ligand 4′-(5-methylfuran-2-yl)-2,2′:6′,2″-terpyridine (1) was prepared in one step from 2-acetylpyridine and 5-methylfurfural. The latter is an aldehyde that can be readily obtained from biomass. The new terpyridine molecule was characterized by 1H and 13C-NMR spectroscopy as well as by ...

Diversity-oriented Synthesis of Spiropyrrolo[1, 2-a]isoquinoline Derivatives via Diastereoselective and Regiodivergent Three-component 1,3-Dipolar Cycloaddition Reactions: In vitro and in vivo Evaluation of the Antidiabetic Activity of Rhodanine Analogues

Collected date : from 2018 to 2021

An efficient diastereoselective route is developed to get access to novel spiropyrrolo[1,2-a]isoquinoline-oxindole skeletons by a one-potthree-component [3 + 2] cycloaddition reaction of (Z)-5-arylidene-1,3-thiazolidine-2,4-diones, isatin derivatives, and 1,2,3,4-tetrahydroisoquinoline (THIQ). ...

Crystal structure of di-[mu]-iodido-bis­[bis(aceto­nitrile-[kappa]N)copper(I)]

The title compound, [Cu2I2(CH3CN)4], exhibits a centrosymmetric Cu2I2 core [Cu...Cu distance = 2.7482 (11) Å], the CuI atoms of which are further coordinated by four mol­ecules of aceto­nitrile. The CuI atom has an overall distorted tetra­hedral coordination environment evidenced by L-Cu-L angles (L ...

Crystal structure of di-[mu]-iodido-bis­[(dimethyl sulfoxide-[kappa]O)(tri­phenyl­phosphane-[kappa]P)copper(I)]

The centrosymmetric dinuclear title compound, [Cu2I2(C2H6OS)2(C18H15P)2], represents the first example of a CuI complex ligated by an O-bound dimethyl sulfoxide ligand. In the crystal, the two tetrahedrally coordinated CuI atoms are bridged by two [mu]2-iodido ligands in an almost symmetrical ...

4,4″-Dichloro-4′-(2-thienyl)-2,2′:6′,2″-terpyridine

Disciplines : chemistry, organic
Collected date : from 2017 to 2018

A new thiophene-substituted terpyridine derivative has been prepared and characterized. This ligand features a thiophene heterocycle (as an electrochemically polymerizable unit) as well as two chlorine atoms for further functionalization.

4′-(N-(Propan-1,2-dienyl)pyrrol-2-yl)-2,2′:6′,2″-terpyridine

Disciplines : chemistry, organic
Collected date : from 2018 to 2019

A new pyrrole-substituted terpyridine derivative that possesses an allene moiety was obtained as an “unexpected” sole product during an attempt to alkylate the N-atom of pyrrole with propargyl bromide in order to obtain an alkyne-functionalized terpyridine.

4′-(5-n-Propylthiophen-2-yl)-2,2′:6′,2″-terpyridine

Disciplines : chemistry, organic
Collected date : 2020

A new thiophene-substituted terpyridine derivative has been prepared through the reaction between 5-n-propylthiophene-2-carboxaldehyde and 2-acetylpyridine. This terpyridine derivative bears an alkyl chain linked via a thiophene heterocycle.

Climate projection over France (8 km resolution) CMIP5

The set of climate projections available corresponds to the GCM (Global Circulation Model) data from CMIP5 (Coupled Model Intercomparison Project; Taylor et al., 2012) used in the fifth IPCC report. A total of 23 GCMs from 16 different institutions were downloaded on the ESGF (Earth System Grid ...

Pollen analysis - Montlebon (F-25), Sur la Vigne 1 (Morteau A)

Collected date : 1982
Creators : Hervé Richard

Natural site: wet meadow. 99 palynological samples + 4 radiocarbon datings. Drilling of 28.10 meters length.

Pollen analysis - Montlebon (F-25), La Vigne 2

Collected date : 1992
Creators : Hervé Richard

Natural site: wet meadow. 22 palynological samples. From 3,90 to 18,85 meters length: extension of Morteau Stade and Sur la Seigne transect lines.

Pollen analysis - Lavancia-Epercy (F-39), Dortan travertine quarry

Collected date : 1985
Creators : Hervé Richard

Natural site: travertine quarry ("Tuff of Dortan"). 3 palynological samples + 1 radiocarbon dating: 9100 ± 180 BP.

Pollen analysis - Montlebon (F-25), Transect S4

Collected date : 1992
Creators : Hervé Richard

Natural site: wet meadow. 6 palynological samples. From 10.20 to 13.20 meters. Atypical results. Extension of Morteau Stade et Sur la Seigne transect lines.

Pollen analysis - Montlebon (Morteau-Montlebon) (F-25), Transects II-6, II-7 et III-7

Collected date : 1992
Creators : Hervé Richard

Natural site; wet meadow. 14 palynological samples. Approximate geographical coordinates: 3 transect lines.

66 results

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Université de Bourgogne, Université de Franche-Comté, UTBM, AgroSup Dijon, ENSMM, BSB, Arts des Metiers