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chemistry, organic
Jérôme Husson
Structure : Institut UTINAM (UMR 6213)
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1-(4-Formyl-2,6-dimethoxyphenoxy)-4-chlorobut-2-yne
Dataset
Disciplines :
chemistry, organic
Collected date : from 2020 to 2021
Keywords :
alkylation
alkynes
ethers (IUPAC Gold Book)
nuclear magnetic resonance (NMR)
O-alkylation
...
Creators :
Jérôme Husson
A reaction of biomass-derived aldehyde synringaldehyde and half an equivalent of 1,4-dichlorobut-2-yne was attempted in order to obtain a bis-aldehyde with an alkyne spacer. The reaction was carried out in a basic media to effect bis O-alkylation, as described in literature for the preparation of ...
4′-(5-Methylfuran-2-yl)-2,2′:6′,2″-terpyridine: A New Ligand Obtained from a Biomass-Derived Aldehyde with Potential Application in Metal-Catalyzed Reactions
Dataset
Disciplines :
chemistry, organic
Collected date : from 2017 to 2018
Keywords :
2-acetylpyridine
catalyst (IUPAC Gold Book)
furan
heterocyclic compounds
nuclear magnetic resonance (NMR)
...
Creators :
Jérôme Husson
Laurent Guyard
The new ligand 4′-(5-methylfuran-2-yl)-2,2′:6′,2″-terpyridine (1) was prepared in one step from 2-acetylpyridine and 5-methylfurfural. The latter is an aldehyde that can be readily obtained from biomass. The new terpyridine molecule was characterized by 1H and 13C-NMR spectroscopy as well as by ...
4,4″-Dichloro-4′-(2-thienyl)-2,2′:6′,2″-terpyridine
Dataset
Disciplines :
chemistry, organic
Collected date : from 2017 to 2018
Keywords :
2-acetylpyridine
heterocyclic compounds
nuclear magnetic resonance (NMR)
terpyridine
thiophene
Creators :
Jérôme Husson
Laurent Guyard
A new thiophene-substituted terpyridine derivative has been prepared and characterized. This ligand features a thiophene heterocycle (as an electrochemically polymerizable unit) as well as two chlorine atoms for further functionalization.
4′-(N-(Propan-1,2-dienyl)pyrrol-2-yl)-2,2′:6′,2″-terpyridine
Dataset
Disciplines :
chemistry, organic
Collected date : from 2018 to 2019
Creators :
Jérôme Husson
Laurent Guyard
A new pyrrole-substituted terpyridine derivative that possesses an allene moiety was obtained as an “unexpected” sole product during an attempt to alkylate the N-atom of pyrrole with propargyl bromide in order to obtain an alkyne-functionalized terpyridine.
4′-(5-n-Propylthiophen-2-yl)-2,2′:6′,2″-terpyridine
Dataset
Disciplines :
chemistry, organic
Collected date : 2020
Keywords :
2-acetylpyridine
chalcogenophene
heterocyclic compounds
nuclear magnetic resonance (NMR)
terpyridine
...
Creators :
Jérôme Husson
Laurent Guyard
A new thiophene-substituted terpyridine derivative has been prepared through the reaction between 5-n-propylthiophene-2-carboxaldehyde and 2-acetylpyridine. This terpyridine derivative bears an alkyl chain linked via a thiophene heterocycle.
1-{4-[(Hexyloxy)methyl]pyridin-2-yl}ethanone
A new member of the 2-acetylpyridine family has been prepared and characterized by NMR and IR spectroscopies.
Diethyl 2,2'-(1,4-phenylenedioxy)diacetate
In the title compound, C14H18O6, a crystallographic center at the centroid of the aromatic ring generates the complete molecule which is planar within 0.085 (1) Å for the non-H atoms. In the crystal, weak C—H⋯O and C—H⋯π interactions link the molecules.