Stephan Koller

Structure : Technische Universität Dortmund

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[μ-Bis(diphenylphosphanyl)methane]-tricarbonyl(μ-p-toluenesulfonylmethylisocyanato)(triphenylphosphane)iron-platinum(Fe-Pt)

The title compound, [FePt(C9H9NO2S)(C18H15P)(C25H22P2)(CO)3], represents a rare example of an isonitrile-bridged heterobimetallic complex (here Pt and Fe) and is an inter­esting precursor for the preparation of heterodinuclear [mu]-amino­carbyne complexes, since the basic imine-type N atom of the ...

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