Alkylation

Translations : alkylation

Frame of reference : NASA Thesaurus

4 results

4′-(N-(Propargyl)pyrrol-2-yl)-2,2′:6′,2′′-terpyridine

Disciplines : chemistry, organic
Collected date : from 2018 to 2019

A new terpyridine molecule, bearing a N-propargylated pyrrole, was prepared and characterized. Its synthesis was based on a Krohnke-type reaction between 2-acetylpyridine and N-propargylpyrrole-2-carboxaldehyde in a basic medium. An allene-containing terpyridine was also obtained as a by-product.

1-{4-[(Hexyloxy)methyl]pyridin-2-yl}ethanone

Disciplines : chemistry, organic
Collected date : 2016
Creators : Florian Charrier

A new member of the 2-acetylpyridine family has been prepared and characterized by NMR and IR spectroscopies.

1-(4-Formyl-2,6-dimethoxyphenoxy)-4-chlorobut-2-yne

Disciplines : chemistry, organic
Collected date : from 2020 to 2021
Creators : Jérôme Husson

A reaction of biomass-derived aldehyde synringaldehyde and half an equivalent of 1,4-dichlorobut-2-yne was attempted in order to obtain a bis-aldehyde with an alkyne spacer. The reaction was carried out in a basic media to effect bis O-alkylation, as described in literature for the preparation of ...

4′-(N-(Propan-1,2-dienyl)pyrrol-2-yl)-2,2′:6′,2″-terpyridine

Disciplines : chemistry, organic
Collected date : from 2018 to 2019

A new pyrrole-substituted terpyridine derivative that possesses an allene moiety was obtained as an “unexpected” sole product during an attempt to alkylate the N-atom of pyrrole with propargyl bromide in order to obtain an alkyne-functionalized terpyridine.

4 results

dat@UBFC

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Université de Bourgogne, Université de Franche-Comté, UTBM, AgroSup Dijon, ENSMM, BSB, Arts des Metiers