Spatial and temporal variability of pelagic and benthic organic matter composition in lake
As part of the QUALILAC project (Influence of the watershed on the functioning of lakes: importance of nutritional quality for couplings between benthic and pelagic environments), monitoring of the origin, quantity and quality of organic matter (OM) available at the water column and benthic level ...
4’-(N-(2-cyanoethyl)pyrrol-2-yl)-2,2’:6’,2’’-terpyridine
Data for the synthesis and caracterization of 4’-(N-(2-cyanoethyl)pyrrol-2-yl)-2,2’:6’,2’’-terpyridine.
4′-(N-(Propargyl)pyrrol-2-yl)-2,2′:6′,2′′-terpyridine
A new terpyridine molecule, bearing a N-propargylated pyrrole, was prepared and characterized. Its synthesis was based on a Krohnke-type reaction between 2-acetylpyridine and N-propargylpyrrole-2-carboxaldehyde in a basic medium. An allene-containing terpyridine was also obtained as a by-product.
Physicochemical characteristics of water and sediment - floodplains of the Ain, Doubs and Loue Rivers - 2015-2016
19 sites (16 wetlands and 3 rivers) with different physicochemical characteristics and distributed along three rivers (Ain, Doubs, and Loue) were sampled. The physicochemical characteristics of the wetlands were measured in situ or after laboratory analysis.
Physicochemical characteristics of water and sediment - Ain River floodplain - 2019-2020
34 sites (16 wetland sites, 15 river sites, and 3 groundwaters) distributed along the Ain River with different physicochemical characteristics were sampled. The physicochemical characteristics of the wetlands were measured in situ or after laboratory analysis.
Bromadiolone en Franche-Comté
Anticoagulant rodenticides (bromadiolone) treatments in Franche-Comté
Monitoring of the vegetation of extensive mountain hay meadows in eastern France (Jura and Vosges)
Diachronic observations of the plant communities of extensive hay meadows in the Jura and the Vosges mountains. The data include 66 old floristic relevés (realized between 2005 and 2009), 66 recent floristic relevés (realized in 2019) and plant community descriptors.
Water vole and plant diversity in a productive hay meadow of the Doubs department
Data of 32 vegetation plots located in a productive hay meadow disturbed by water voles. It includes the plant species lists and the associated community descriptors.
Stone crushing and plant community diversity in dry calcareous grasslands (old Franche-Comté region, eastern France)
30 floristic relevés realized in 2019 in dry calcareous grassland sites (in areas disturbed by stone crushing and non-disturbed areas) as well as the description of the studied dry calcareous grasslands.
1-{4-[(Hexyloxy)methyl]pyridin-2-yl}ethanone
A new member of the 2-acetylpyridine family has been prepared and characterized by NMR and IR spectroscopies.
New spiropyrrolothiazole derivatives bearing an oxazolone moiety as potential antidiabetic agent: Design, synthesis, crystal structure, Hirshfeld surface analysis, ADME and molecular docking studies
In a sustained search for novel and effective antihyperglycemics, a new series of fifteen isomeric oxazolone-fused dispiropyrrolothiazoles resulting from one-pot three component reaction between L-4-thiazolidine carboxylic acid, arylidene-oxazolones and isatin (or acenaphthenequinone) has been ...
Antimicrobial Activity and DFT Studies of a Novel Set of Spiropyrrolidines Tethered with Thiochroman-4-one/Chroman-4-one Scaffolds
A novel series of 14 spiropyrrolidines bearing thiochroman-4-one/chroman-4-one, and oxindole/acenaphthylene-1,2-dione moieties were synthesized and characterized by spectroscopic techniques, as well as by three X-ray diffraction studies, corroborating the stereochemistry. Quantum chemical ...
Synthesis, antidiabetic activity and molecular docking study of rhodanine-substitued spirooxindole pyrrolidine derivatives as novel α-amylase inhibitors
In a sustained search for novel α-amylase inhibitors for the treatment of type 2 diabetes mellitus (T2DM), we report herein the synthesis of a series of nineteen novel rhodanine-fused spiro[pyrrolidine-2,3′-oxindoles]. They were obtained by one-pot three component [3 + 2] cycloaddition of stabilized ...
Pollen analysis - Les Rousses (F-39), Les Rousses lake
Natural site: peat bog near the lake's outlet. 16 palynological samples. The selection was made in several drillings. Two pollen tests performed in 2021 towards the lake outlet.
1-(4-Formyl-2,6-dimethoxyphenoxy)-4-chlorobut-2-yne
A reaction of biomass-derived aldehyde synringaldehyde and half an equivalent of 1,4-dichlorobut-2-yne was attempted in order to obtain a bis-aldehyde with an alkyne spacer. The reaction was carried out in a basic media to effect bis O-alkylation, as described in literature for the preparation of ...
4′-(5-Methylfuran-2-yl)-2,2′:6′,2″-terpyridine: A New Ligand Obtained from a Biomass-Derived Aldehyde with Potential Application in Metal-Catalyzed Reactions
The new ligand 4′-(5-methylfuran-2-yl)-2,2′:6′,2″-terpyridine (1) was prepared in one step from 2-acetylpyridine and 5-methylfurfural. The latter is an aldehyde that can be readily obtained from biomass. The new terpyridine molecule was characterized by 1H and 13C-NMR spectroscopy as well as by ...
Diversity-oriented Synthesis of Spiropyrrolo[1, 2-a]isoquinoline Derivatives via Diastereoselective and Regiodivergent Three-component 1,3-Dipolar Cycloaddition Reactions: In vitro and in vivo Evaluation of the Antidiabetic Activity of Rhodanine Analogues
An efficient diastereoselective route is developed to get access to novel spiropyrrolo[1,2-a]isoquinoline-oxindole skeletons by a one-potthree-component [3 + 2] cycloaddition reaction of (Z)-5-arylidene-1,3-thiazolidine-2,4-diones, isatin derivatives, and 1,2,3,4-tetrahydroisoquinoline (THIQ). ...
4,4″-Dichloro-4′-(2-thienyl)-2,2′:6′,2″-terpyridine
A new thiophene-substituted terpyridine derivative has been prepared and characterized. This ligand features a thiophene heterocycle (as an electrochemically polymerizable unit) as well as two chlorine atoms for further functionalization.
4′-(N-(Propan-1,2-dienyl)pyrrol-2-yl)-2,2′:6′,2″-terpyridine
A new pyrrole-substituted terpyridine derivative that possesses an allene moiety was obtained as an “unexpected” sole product during an attempt to alkylate the N-atom of pyrrole with propargyl bromide in order to obtain an alkyne-functionalized terpyridine.
4′-(5-n-Propylthiophen-2-yl)-2,2′:6′,2″-terpyridine
A new thiophene-substituted terpyridine derivative has been prepared through the reaction between 5-n-propylthiophene-2-carboxaldehyde and 2-acetylpyridine. This terpyridine derivative bears an alkyl chain linked via a thiophene heterocycle.
Pollen analysis - Fontenu (F-39), îlot David-1987, FG 30, 86 S-C, 86 G23
Archaeological site. Lake dwelling. 9 palynological samples (related to M. Magny PhD thesis, 1991).
Pollen analysis - Bonlieu (F-39), Le Lautrey (point 205)
Peat bog; 51 palynological samples. Other analyses on this site by Carole Bégeot and Pascale Ruffaldi (2006)
Pollen analysis - Corsier (Suisse, Genève), Marina
Lacustrin archaeological site: sub-lake drilling. 25 palynological samples in the core C1
Pollen analysis - Ponsonby (Chili, Provincia Ultima Esperenza, Patagonia Austral), Emperaire/Legoupil excavations (Riesco Island)
Sections in an archaeological site. 146 palynological samples + 7 radiocarbon datings. 3 series: pingüino, locus 1 (very poor) et locus 2.
Pollen analysis - Montlebon (F-25), La Vigne 2
Natural site: wet meadow. 22 palynological samples. From 3,90 to 18,85 meters length: extension of Morteau Stade and Sur la Seigne transect lines.
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